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Silica is one of the key materials in many modern technological applications. Further miniaturization of nanoelectronic devices necessitates rational design of ultrathin silica films on electrically conductive substrates. This is the first-ever book on the preparation and atomic-level description of ultrathin silica films grown on metal substrates. Experimental and theoretical studies performed in recent years provide compelling evidence of the growth of well-ordered silica films that exhibit the structural motif of sheet silicates. A growing body of research suggests that a singlelayer silicate, which received the name silicatene by analogy with the famous graphene, should be included in the family of truly two-dimensional materials. In addition, the silicate films modified with metals such as Al and Fe offer a unique possibility to study the surface structures (and hence the surface chemistry) of natural silicates, e.g., clays and zeolites. Finally, ultrathin silica films represent well-defined model systems for elucidating the mechanism of crystal-glass transitions.
Organic LEDs (OLEDs) in mobile displays have been in large-scale production for over a decade, and OLED-based televisions are rapidly gaining traction in the marketplace. OLEDs are on the verge of entering the solid-state lighting market in a big way.
Professionals recognize entropy-enthalpy compensation as an important factor in molecular recognition, lead design, water networks, and protein engineering. It can be experimentally studied by proper combinations of diverse spectroscopic approaches with isothermal titration calorimetry and is clearly related to molecular dynamics. So, how should we treat entropy-enthalpy compensation? Is it a stubborn hindrance that solely complicates the predictability of phenomena otherwise laid on the line by Mother Nature? How should we then deal with it? This book dwells on these posers. It combines two chapters written by globally recognized specialists. Chapter 1 deals with general issues and suggests a definite approach to how we may answer the posers. Chapter 2 shows how the approach outlined might be successfully applied in a rational design of enzymes. This might provide other interesting strategic perspectives in the general theoretical physical chemistry field.
This book fills this gap and shines more light on the role of electrolytes in modern batteries. Today, limitations in lithium-ion batteries result from non-optimal properties of commercial electrolytes as well as scientific and engineering challenges related to novel electrolytes for improved lithium-ion as well as future post-lithium batteries.
The book highlights some of the issues surrounding this missing link by providing a detailed review of the nanostructure and electronic properties, materials, and device fabrication and of the structure-property-application relationships.
This volume of Pharmaceutical Biocatalysis starts with a discussion on the importance of biocatalytic synthesis approaches for a sustainable and environmentally friendly production of pharmaceuticals and active pharmaceutical ingredients.
Mullite is the most important crystalline phase in fired products belonging to the Al2O3-SiO2 mullite system, such as whiteware articles used in daily life (e.g., low- and high-temperature hard porcelain, sanitaryware, and structural clay products). Mullite has attracted increasing interest due to its excellent high-temperature strength and creep resistance, good chemical and thermal stability, low thermal expansion coefficient, and good dielectric properties. Mullitization has been a subject of extensive and controversial investigations. This book comprehensively covers the synthesis and six types of phase transformation of mullite. Part I reviews previous research on the synthesis of mullite gels, advantages and disadvantages of different chemical routes of synthesis, and phase transformation processes. Part II discusses the nature and characterization of spinel and mullite phases and different mechanisms of mullite formation, as conjectured by various researchers. Part III deals with the critical analysis of the spinel and mullite phases and evolution of mullite formation routes. Every chapter is accompanied by detailed diagrams and a comprehensive list of references.
The era of Sustainable and Energy Efficient Nanoelectronics and Nanosystems has come. The research and development on Scalable and 3D integrated Diversified functions together with new computing architectures is in full swing.
Volume 7 of the Jenny Stanford Series on Biocatalysis deals with several different aspects of pharmaceuticals, which include not only various applications of drugs and their metabolism but also natural resources for active pharmaceutical ingredients as well as the removal of pharmaceutical pollution.
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